通过水热法制备了具有交联结构的聚丙烯酸酯(PAAS)-聚乙烯醇(PVA)-纳米SiO2有机无机复合乳液,并将该乳液通过提拉在玻璃基底和PET膜上构建了性能稳定、透明的亲水涂层.研究了乳液中纳米颗粒掺入量对涂层表面形貌、润湿性和透光率的影响,结果表明,随着纳米粒子掺入量的增加,涂层亲水性随之增大,而透过率随之下降.当PVA含量为0.25wt％,PAAS、PVA和SiO2的质量比为1:2.5:10时,涂层亲水性长效稳定,一个月时间内接触角保持在5°左右,在500～ 760nm波长范围内透过率超过78.68％,硬度达到HB.常温聚丙烯酸酯-聚乙烯醇-纳米SiO2亲水涂层具有稳定的耐水性和良好的抗结霜和快速除霜性能.
参考文献
| [1] | Zhao J;Meyer A;Ma L;Ming W .Acrylic coatings with surprising antifogging and frost-resisting properties[J].Chemical Communications,2013,49(100):11764-11766. |
| [2] | Chevallier P;Turgeon S;Sarra-Bournet C;Turcotte R Laroche G .Characterization of multilayer anti-fog coatings[J].ACS Applied Materials & Interfaces,2011(3):750-758. |
| [3] | Lai Y;Tang Y;Gong J;Gong D Chi L Lin C Chen Z .Transparent super-hydrophobic/super-hydrophilic TiO2-based coatings for self-cleaning and anti-fogging[J].Journal of Materials Chemistry,2012,22(15):7420-7426. |
| [4] | Zhao C;Chappell Jr C .Silicate-containing antifog coatings[P].US,14/052,245,2013-10-11. |
| [5] | Jia Y;Liu G;Wu X;Liu H Yue R Chen Y .Anti-fogging and anti-reflective silica nano-fibrous film fabricated by seedless flame method[J].Materials Letters,2013,108:200-203. |
| [6] | Yuan Y;Liu R et al.Synthesis of UV-curable acrylate polymer containing sulfonic groups for anti-fog coatings[J].Progress in organic Coatings,2014,77(4):785-789. |
| [7] | 沙鹏宇,刘岩,谢雷,崔占臣.亲水性有机硅杂化防雾涂料的制备及性能[J].高等学校化学学报,2007(11):2205-2209. |
| [8] | Chang C C;Wang K C;Chen C C;Cheng L P .Preparation and characterization of silica/polymer antifogging coatings[J].Polymers&Polymer Composites,2014,22(1):39-44. |
| [9] | 孟丹,王和义,刘秀华.TiO2光催化剂的掺杂改性研究进展[J].材料导报,2010(z2):58-62. |
| [10] | 周立国,刘晓妍,王玉兵.一种Gemini表面活性剂合成及其在薄膜中的应用[J].化学研究与应用,2012(06):890-894. |
| [11] | 余家国,赵修建,林立,韩建军,赵青南.超亲水TiO2/SiO2复合薄膜的制备与表征[J].无机材料学报,2001(03):529-534. |
| [12] | 许利刚,李晓禹,贺军辉.层层自组装结合后处理制备耐磨超亲水增透纳米粒子涂层[J].化学学报,2011(22):2648-2652. |
| [13] | Li K;Zeng X;Li H;Lai X .Fabrication and characterization of stable superhydrophobic fluorinated-polyacrylate/silica hybrid coating[J].Applied Surface Science,2014,298:214-220. |
| [14] | 刘湘梅,贺军辉.防雾技术的研究进展--从表面工程到功能表面[J].化学进展,2010(02):270-276. |
| [15] | Joki-Korpela F;Karvinen J et al.Hydrophobic and oleophobic anti-reflective polyacrylate coatings[J].Microelectronic Engineering,2014,114:38-46. |
| [16] | Yilmaz O .A hybrid polyacrylate/OMMT nanocomposite latex:Synthesis,characterization and its application as a coating binder[J].Progress in organic Coatings,2014,77(1):110-117. |
| [17] | 张启忠,王澍,刘仲,殷绿.聚丙烯酸酯透明防结露涂料的研制[J].涂料工业,2012(01):39-41,49. |
| [18] | Zhao F;Zeng X;Li H;Guo J .Preparation of fluorinated polyacrylate composite latex with in situ generated nano-silica dispersion and film durability[J].IRANIAN POLYMER JOURNAL,2013,22(10):775-784. |
| [19] | 刘爱红,姜发堂.魔芋超强吸水剂（KSAP）的结构分析[J].材料科学与工程学报,2007(06):826-829. |
| [20] | 饶思奇,回琳,邓敏,徐祖顺,张全元.甲基丙烯酸缩水甘油酯交联壳聚糖/聚乙烯醇水凝胶薄膜的制备及性能[J].材料科学与工程学报,2014(4):543-547,562. |
| [21] | 丁利,杨红梅,杨永柱.LDPE/PVA吸湿功能材料的熔融复合制备[J].材料科学与工程学报,2008(06):904-907,877. |
| [22] | 刘翠云,姚大虎,陈权,张玉清.PAA-Na/PVA半互穿网络水凝胶的离子强度及pH敏感性[J].化工新型材料,2012(07):97-99. |
| [23] | 孙紫红,袁安保.PVA-PAAS基碱性聚合物电解质的制备及性能[J].电源技术,2007(10):804-807. |
| [24] | Tan Q;Yu G;Liao Y et al.Preparation of stable aqueous suspensions of antimony-doped tin oxide nanoparticles used for transparent and thermal insulation fluorocarbon coating[J].Colloid and Polymer Science,2014,292(12):3233-3241. |
| [25] | 史丽萍,路琴,顾红艳,何春霞.纳米SiO2粒子填充不饱和聚酯树脂基复合材料的摩擦学性能[J].材料科学与工程学报,2011(01):39-41,52. |
| [26] | 张静,何春霞,路琴.不同纳米粒子填充PA6/GF复合材料摩擦磨损性能[J].材料科学与工程学报,2009(03):480-482,454. |
| [27] | Chang C C;Oyang T Y;Chen Y C;Hwang F H Cheng L P .Preparation of hydrophobic nanosilica-filled polyacrylate hard coatings on plastic substrates[J].Journal of Coatings Technology and Research,2014,11(3):381-386. |
| [28] | 李秀玲,杨帅,刘俊杰,李萌,杨旭.有机硅改性丙烯酸树脂性能研究[J].现代涂料与涂装,2012(01):1-2,36. |
| [29] | Zhou G;He J;Xu L .Antifogging antireflective coatings on Fresnel lenses by integrating solid and mesoporous silica nanoparticles[J].Microporous and Mesoporous Materials,2013,176:41-47. |
| [30] | Chen R;Zhang X;Su Z et al.Perfectly hydrophobic silicone nanofiber coatings:Preparation from methyltrialkoxysilanes and use as water-collecting substrate[J].The Journal of Physical Chemistry C,2009,113(19):8350-8356. |
| [31] | 黄玲艳 .表面特性对冷壁面结霜过程影响的研究[D].北京工业大学,2011. |
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